Silver-Catalysed CO2 Incorporation Reactions

Author(s): Dr. S.K. Mishra

Publication #: 2301008

Date of Publication: 10.01.2023

Country: India

Pages: 1-13

Published In: Volume 9 Issue 1 January-2023

Abstract

Silver-catalyzed reactions are some of the important methodologies in organic chemistry. For the sequential carboxylation and cyclization of alkyne derivatives, such as propargyl alcohols and amines, using carbon dioxide, silver catalysts show significant reactivity under mild conditions unlike other transition metals. Related silver-catalyzed C–C bond forming reactions with carbon dioxide have also provided the synthetic methods of the corresponding carboxylic acid derivatives.

Keywords: Carbon dioxide, Silver catalyst, Alkyne, Cyclic carbonate, Heterocycle

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