Crystal structure and Characterization of Tris (Morpholino) Silane: (OC4H8N)3SiH
Author(s): Dr. K.N. Radhamani
Publication #: 2404076
Date of Publication: 28.04.2024
Country: India
Pages: 1-5
Published In: Volume 10 Issue 2 April-2024
Abstract
The structure of tris(morpholino)silane has been determined in the solid state. The compound crystallised in monoclinic form. The refinement converged to a final R value of 0.0512 and wR = 0.0585 with weighing schemes based on counting statistics, where W = 0.001931 and final (shift/esd) max = 0.385. The molecular parameters obtained are Si—N1 = 1.692, Si-N2 = 1.699, Si-N3 = 1.695. The ˂N2-Si-N3 = 120, ˂N1-Si-N3 = 106, ˂N1-Si-N2 = 106. The Si and N NMR, FT-IR spectroscopy was used to characterize the compound. Since all nitrogen atoms were almost planar according to the bond angle obtained from crystallographic studies, it suggest a strong (p-d)π interactions and Si-N bonding.
Keywords: Tri(amino)silane, N NMR, Si NMR, Morpholine
Download/View Count: 221
Share this Article